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Bake brownies as directed, but for only 20 mins at 350F. Use cupcake liners in cupcake pan instead of brownie pan.
After brownies are done, put them on the counter to cool. With brownies still warm on counter (in liners), melt peanut butter in a double boiler (or make-shift if you don't own one--we don't).
Pour peanut butter over top of brownies in cupcake liner. Smooth out peanut butter as necessary with a spoon.
Put brownies in the freezer while the chocolate is melting to help solidify the peanut butter.
Put completed cupcakes back in the freezer to cool, until the chocolate hardens.
When they are solid, remove from freezer and enjoy! Recommend you enjoy them with friends so that you don't die of a heart attack.