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Tap on settings

Tap on wifi

Turn off ask to join, this will stop your iPhone from trying to connect to any network and will save you some battery

If there is a network your phone has already joined and you want to get rid of tap on its name, for the sake of this guide I will delete the orange network

Tap on forget this network, this is it this network won't bother you anymore and your phone will only connect to your chosen networks. Enjoy